Alcohol activation by [Ir (COD) (tris (pyrazol-1-yl) methane)]+ and [Ir (COD)(tris(pyrazol-1-yl)ethane]+ cations: formation of alkoxycarbonyl derivatives [(tpzm)IrH(CO2R?)(CO)]+ and [(tpze)IrH(CO2R?)(CO)]+ [R?=Me, Et, i-Pr)

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dc.centroUniversidad San Pablo-CEU
dc.contributor.authorEsteruelas, Miguel A.es
dc.contributor.authorOro, Luis A.
dc.contributor.authorClaramunt, Rosa María
dc.contributor.authorLópez, Concepción
dc.contributor.authorElguero, José
dc.contributor.authorLavandera Díaz, José Luis
dc.date1989es
dc.date.accessioned2013-10-26T04:00:21Z
dc.date.available2013-10-26T04:00:21Z
dc.date.issued1989-10-26
dc.descriptionArtículo en colaboración con : Miguel A. Esteruelas, Luis A. Oro, Rosa M. Claramunt, Concepción López y José Elgueroes
dc.descriptionEn: Journal of Organometallic Chemistry. ISSN 0022-328x. n. 366, 1989, págs 245-255es
dc.description.abstractThe reactions of iridium and rhodium complexes derived from tris(pyrazolyl)methane (tpzm) and tris(pyrazolyl)ethane (tpze) have been examined. One of the most interesting reactions involves the formation of alkoxycarbonyl derivatives of iridium tris(pyrazolyl)alkanes from carbon monoxide and alcohols. In the case of rhodium derivatives, a dimer of formula [(tpzm)iRh2 (CO)3](ClO4h has been obtained. A careful 1H and 13C NMR study has allowed assignment of all the signals of the compound [(tpzm)IrH(CO2Me)(CO)]BF4en_EN
dc.formatapplication/pdfes
dc.identifier000000580554es
dc.identifier.urihttp://hdl.handle.net/10637/5513
dc.language.isoenes
dc.rights.cchttps://creativecommons.org/licenses/by-nc-nd/4.0/deed.es
dc.subjectCompuestos heterocíclicos.es
dc.titleAlcohol activation by [Ir (COD) (tris (pyrazol-1-yl) methane)]+ and [Ir (COD)(tris(pyrazol-1-yl)ethane]+ cations: formation of alkoxycarbonyl derivatives [(tpzm)IrH(CO2R?)(CO)]+ and [(tpze)IrH(CO2R?)(CO)]+ [R?=Me, Et, i-Pr)es
dc.typeArtículoes
dspace.entity.typePublicationes
europeana.dataProviderUNIVERSIDAD SAN PABLO CEU
europeana.isShownAthttp://hdl.handle.net/10637/5513
europeana.objecthttp://repositorioinstitucional.ceu.es/visor/libros/580554/thumb_europeana/580554.jpg
europeana.providerHispana
europeana.rightshttp://creativecommons.org/publicdomain/zero/1.0/
europeana.typeTEXT
relation.isAuthorOfPublication4b2f346e-6109-4faa-98e2-394f41e4f7f9
relation.isAuthorOfPublication.latestForDiscovery4b2f346e-6109-4faa-98e2-394f41e4f7f9

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