Escuela de Politécnica Superior

Recently, studies on sustainability and ecology have become widespread in almost all sectors. One of the most important reasons for this spread is the rapid increase in industrialization and, thus, the increase in waste caused by industries. In this context, significant efforts are being made to evaluate some of these wastes. One of these efforts is the production of geopolymers. In this research, metakaolin and slag-based geopolymer mortar samples were manufactured, and polyvinyl Alcohol, basalt, and macro synthetic polypropylene fibers were used to enhance the physical, mechanical, and high-temperature resistance of the sample. Physical and mechanical tests of the produced samples were performed after 28 days. Then, elevated-temperature experiments were conducted to evaluate the behavior of the fibers under the influence of high temperature. Following the high-temperature test, physical, mechanical and microstructure tests of the samples were performed. As a result, basalt fiber enhanced the compressive strength of 800 ◦C-exposed samples by 7.72% compared to the fiber-free sample. Also, polyvinyl Alcohol fiber increased the energy absorption capacity of the samples by increasing Charpy impact values to 72.22% compared to fiber-free sample. Moreover, macro synthetic polypropylene fiber reduced capillary water absorption value up to 12.44% compared to fiber-free sample.

Concrete made with Portland cement is by far the most heavily used construction material in the world today. Its success stems from the fact that it is relatively inexpensive yet highly versatile and functional and is made from widely available raw materials. However, in many environments, concrete structures gradually deteriorate over time. Premature deterioration of concrete is a major problem worldwide. Moreover, cement production is energy-intensive and releases a lot of CO2; this is compounded by its ever-increasing demand, particularly in developing countries. As such, there is an urgent need to develop more durable concretes to reduce their environmental impact and improve sustainability. To avoid such environmental problems, researchers are always searching for lightweight structural materials that show high performance during both processing and application. Among the various candidates, Magnesia (MgO) seems to be the most promising material to attain this target. This paper presents a comprehensive review of the characteristics and developments of MgO-based composites and their applications in cementitious materials and energy-efficient buildings. This paper starts with the characterization of MgO in terms of environmental production processes, calcination temperatures, reactivity, and micro-physical properties. Relationships between different MgO composites and energy-efficient building designs were established. Then, the influence of MgO incorporation on the properties of cementitious materials and indoor environmental quality was summarized. Finally, the future research directions on this were discussed.

Unlike conventional concrete materials, Engineered Cementitious Composites (ECC) use a micromechanics-based design theory in the material design process. Recently, the use of nanoparticles in various concretes and mortars has increased. This study used nanocalcite to investigate the mechanical, microstructural fractal analysis of environmentally friendly nanocalcite-doped ECC (NCa-ECC). This paper investigated the effects of nanocalcite (NCa) with different contents (0.5, 1, and 1.5% by mass of binder) on the mechanical properties of engineered cementitious composites (ECC). For this purpose, compressive strength, ultrasonic pulse velocity (UPV), and flexural strength tests were conducted to investigate the mechanical properties of the ECC series. In addition, SEM analyses were carried out to investigate the microstructural properties of the ECC series. The content of nanocalcite improved the mechanical and microstructural properties of the nanocalcite-modified ECC series. In addition, the 1 NCa series (1% nanocalcite modified to the mass of the binder) had the best performance among the series used in this study.

As the human population grows and technology advances, the demand for concrete and cement grows. However, it is critical to propose alternative ecologically suitable options to cement, the primary binder in concrete. Numerous researchers have recently concentrated their efforts on geopolymer mortars to accomplish this objective. The effects of basalt fiber (BF) on a geopolymer based on fly ash (FA) and basalt powder waste (BP) filled were studied in this research. The compressive and flexural strength, Charpy impact, and capillary water absorption tests were performed on produced samples after 28 days. Then, produced samples were exposed to the hightemperature test. Weight change, flexural strength, compressive strength, UPV, and microstructural tests of the specimens were performed after and before the effect of the high temperature. In addition, the results tests conducted on the specimens were compared after and before the high-temperature test. The findings indicated that BF had beneficial benefits, mainly when 1.2 percent BF was used. When the findings of samples containing 1.2 percent BF exposed to various temperatures were analyzed, it was revealed that it could increase compressive strength by up to 18 percent and flexural strength by up to 44 percent. In this study, the addition of BF to fly ash-based geopolymer samples improved the high-temperature resistance and mechanical properties.