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dc.contributor.otherUCH. Departamento de Farmacia-
dc.contributor.otherProducción Científica UCH 2017-
dc.creatorGonzález Rosende, María Eugenia.-
dc.creatorCastillo García, Encarnación.-
dc.creatorJennings, W. Brian.-
dc.creatorMalone, John F.-
dc.date2017-
dc.date.accessioned2019-09-25T04:00:11Z-
dc.date.available2019-09-25T04:00:11Z-
dc.date.issued2017-01-17-
dc.identifier.citationGonzález-Rosende, ME., Castillo García, E., Jennings, WB. & Malone, JF. (2017). Stereodynamics and Edge-to-Face CH-π aromatic interactions in imino compounds containing heterocyclic rings. Organic & Biomolecular Chemistry, n. 6. DOI: https://doi.org/10.1039/C6OB02618D-
dc.identifier.issn1477-0520-
dc.identifier.issn1477-0539 (Electrónico)-
dc.identifier.urihttp://hdl.handle.net/10637/10592-
dc.descriptionEste es el post-print que se ha publicado de forma definitiva en: https://pubs.rsc.org/en/content/articlelanding/2017/ob/c6ob02618d#!divAbstract-
dc.description.abstractBy comparison with close contact interactions between benzene rings there is a paucity of experimental data available for attractive interactions involving aromatic heterocyclic rings, especially for small molecules in solution. Herein we describe aromatic heterocyclic and carbocyclic edge-to face interactions and conformational stereodynamics of N-1,2-diphenylethyl imines bearing a phenyl group and either a 2-pyridyl, 3-pyridyl, 2-thiophene or 2-furanyl moiety on the imino carbon. X-ray crystal structures have been determined for two compounds. Slow rotation about the phenyl–imino bond in the E-isomers and around the heterocycle–imino bond in the Z-isomers of the pyridyl compounds was observed at low temperatures by NMR. Abnormally large shielding of one ortho hydrogen indicates that both the imino phenyl and heterocycle rings can engage in an edge-to-face interaction with the N-terminal phenyl moiety in the appropriate isomer. Some rotational barriers around the phenyl–imino and heterocycle–imino bonds were measured.-
dc.formatapplication/pdf-
dc.languagees-
dc.language.isoen-
dc.publisherRoyal Society of Chemistry-
dc.relation.ispartofOrganic & Biomolecular Chemistry, n. 6 (17 jan. 2017).-
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/4.0/deed.es-
dc.subjectCompuestos heterocíclicos.-
dc.subjectChemistry, Organic.-
dc.subjectQuímica orgánica.-
dc.subjectHeterocyclic compounds.-
dc.titleStereodynamics and Edge-to-Face CH-π aromatic interactions in imino compounds containing heterocyclic rings-
dc.typeArtículo-
dc.description.versionThis is the peer reviewed version of the following article: González-Rosende, ME., Castillo García, E., Jennings, WB. & Malone, JF. (2017). Stereodynamics and Edge-to-Face CH-π aromatic interactions in imino compounds containing heterocyclic rings. Organic & Biomolecular Chemistry, n. 6, which has been published in final form at https://doi.org/10.1039/C6OB02618D.-
dc.description.versionEsta es la versión post-print del siguiente artículo: González-Rosende, ME., Castillo García, E., Jennings, WB. & Malone, JF. (2017). Stereodynamics and Edge-to-Face CH-π aromatic interactions in imino compounds containing heterocyclic rings. Organic & Biomolecular Chemistry, n. 6, que se ha publicado de forma definitiva en https://doi.org/10.1039/C6OB02618D-
dc.identifier.doihttps://doi.org/10.1039/C6OB02618D-
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